مقالۀ پژوهشی: افزایش بازده سلول خورشیدی سیلیکونی با تبدیل طیف فرابنفش به مرئی با استفاده از نانو ذرات فسفر قرمز

نوع مقاله : مقاله پژوهشی

نویسنده

پژوهشگر، گروه فیزیک حالت جامد، دانشکده فیزیک، دانشگاه صنعتی شاهرود، شاهرود، ایران

چکیده

نانو ذرات فسفر قرمز بر سطح سلول خورشیدی سیلیکونی به روش لایه‌نشانی تبخیر حرارتی فیزیکی (چگالش بر روی سطح سلول از فاز بخار) سنتز شد. لایه‌نشانی فسفر قرمز بر سطح سلول‌ها چندین بار با ضخامت‌های مختلفی از لایه‌ی فسفر تکرار شد و بعد از هر مرحله لایه‌نشانی بازده سلول خورشیدی سیلیکونی اندازه‌گیری شد. نتایج نشان داد که بعد لایه‌نشانی 340 نانومتر فسفر بازده سلول از 86/5 به 08/7 درصد افزایش یافته و حدود 21 درصد افزایش بازده نسبی حاصل شده است. علاوه بر آن نتایج طیف جذبی و فوتولومینسانس لایه‌ها نشان داد نانوذرات فسفر قرمز نور فرابنفش را جذب کرده و نور مرئی علاوه بر فرابنفش گسیل کرده‌اند. به عبارت دیگر لایه‌ی فسفر نور فرابنفش را به ناحیه‌ی طول موج مرئی جابجا می‌نماید. در این تحقیق از سلول خورشیدی سیلیکونی تک‌بلوری برای افزایش بازده استفاده شد و فسفر قرمز آمورف به روش تبخیر حرارتی فیزیکی بر سطح سلول خورشیدی سیلیکونی لایه‌نشانی شد. همچنین برای انجام طیف‌سنجی نوری، لام شیشه‌ای در کنار سلول‌ها در هر مرتبه لایه‌نشانی قرار داده شد. نتایج طیف‌سنجی نوری لایه‌های فسفر همچنین نشان داد میزان عبور نور فرابنفش در نمونه‌ی دارای 340 نانومتر لایه‌ی فسفر نسبت به نمونه‌ی دارای 50 نانومتر لایه‌ی فسفر کمتر است و برعکس میزان جذب نور بیشتر است، به عبارت دیگر لایه‌های ضخیم‌تر فسفر نور فرابنفش را کمتر عبور می‌دهند و بیشتر جذب می‌کنند.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Red Phosphorus Nanoparticles in the Silicon Solar Cells for Higher Cell Efficiency and Converting the Ultraviolet to Visible Light Wavelength Range

نویسنده [English]

  • Saeed Salehpour
Researcher, Solid State Physics Department, Faculty of Physics, Shahrood University of Technology, Shahrood, Iran.
چکیده [English]

Red phosphorus nanoparticles were synthesized on the surface of the silicon solar cell by PVD technique (condensation on the cell surface from the vapor phase). The red phosphorous deposition on the surface of the cells was repeated several times with different thicknesses of the phosphorous layer, and after each deposition procedure, the efficiency of the silicon solar cell was measured. The obtained results demonstrated that after the deposition of 340 nm of phosphorous, the efficiency of the cell increased from 5.86 to 7.08, and about a 21% relative increase in efficiency was achieved. Moreover, the layers' absorption spectra and photoluminescence spectrum show that red phosphorus nanoparticles absorbed UV light and emitted visible light in addition to UV. In other words, the phosphorous layer has shifted the UV light to the visible light wavelength. In this research, a monocrystalline silicon solar cell was used to increase efficiency, and amorphous red phosphorus was deposited on the surface of the silicon solar cell by the PVD technique. In addition, to perform optical spectroscopy, a glass slide was placed next to the cells in each deposition step. The results of optical spectroscopy of phosphorous layers also showed that the amount of UV light transmission in the sample with a 340 nm phosphorous layer is lower than the sample with a 50 nm phosphorous layer. And vice versa, the amount of UV light absorption is higher, in other words, thicker phosphorous layers pass UV light less and absorb it more. 

کلیدواژه‌ها [English]

  • Nanoparticles
  • Silicon Solar Cell
  • Efficiency
  • Phosphorus
[1] S. Bera, S. Mondal, A. Majumder, S. Paul, et al., "A potential roadmap on the development, application, and loopholes of metal-organic frameworks in high-performance third-generation solar cells", Chemistry of Inorganic Materials, 1, 100024, 2023. https://doi.org/10.1016/j.cinorg.2023.100024
[2] M. F. Rahman, M. K. Hasan, M. Chowdhury, M. R. Islam, et al., "A qualitative Design and optimization of CIGS-based Solar Cells with Sn2S3 Back Surface Field: A plan for achieving 21.83 % efficiency", Heliyon 9 (12), e22866, 2023. https://doi.org/10.1016/j.heliyon.2023.e22866
[3] A. Pattnaik, Shivangi and M. Kumar, "Improving the short wavelength response of the multi-crystalline silicon solar cell by using 10% Erbium doped ZnS nanoparticle-based downshifting layer", Results in Optics 12, 100459, 2023. https://doi.org/10.1016/j.rio.2023.100459
[4] C.-K. Wu, S. Zou, C.-W. Peng, S.-W. Gu, et al., "Improving the UV-light stability of silicon heterojunction solar cells through plasmon-enhanced luminescence downshifting of YVO4:Eu3+, Bi3+ nanophosphors decorated with Ag nanoparticles", Journal of Energy Chemistry 81, 212-220, 2023. https://doi.org/10.1016/j.jechem.2023.01.050
[5] A. P. B. Saffar, B.D., "Thermal effects investigation on electrical properties of silicon solar cells treated by laser irradiation", Int. Journal of Renewable Energy Development 3 (3), 184-187, 2014. https://doi.org/10.14710/ijred.3.3.184-187
[6] M. F. Abdelbar, M. Abdelhameed, M. Esmat, M. El-Kemary, et al., "Energy management in hybrid organic-silicon nanostructured solar cells by downshifting using CdZnS/ZnS and CdZnSe/ZnS quantum dots", Nano Energy 89, 106470, 2021. https://doi.org/10.1016/j.nanoen.2021.106470
[7] M. F. Abdelbar, M. El-Kemary and N. Fukata, "Downshifting of highly energetic photons and energy transfer by Mn-doped perovskite CsPbCl3 nanocrystals in hybrid organic/silicon nanostructured solar cells", Nano Energy 77, 105163, 2020. https://doi.org/10.1016/j.nanoen.2020.105163
[8] L. Pei, X.-K. Gong, L. Li, Z.-H. Ma, et al., "3D surface microstructure of silicon modified by QDs to improve solar cell performance through down-conversion and anti-reflection mechanism", Colloids and Surfaces A: Physicochemical and Engineering Aspects 675, 132015, 2023. https://doi.org/10.1016/j.colsurfa.2023.132015
[9] C.-K. Wu, S. Zou, C.-W. Peng, S.-W. Gu, et al., "Improving the UV-light stability of silicon heterojunction solar cells through plasmon-enhanced luminescence downshifting of YVO4:Eu3+, Bi3+ nanophosphors decorated with Ag nanoparticles", Journal of Energy Chemistry 81, 212-220, 2023. https://doi.org/10.1016/j.jechem.2023.01.050
[10] X. Ma, Y. Chen, Y. Liu, X. Zhang, et al., "Ce3+-Yb3+, Tb3+-Yb3+ and Pr3+-Nd3+-Yb3+ mixed-doped TeO2–ZnO–Na2O glasses for enhancing the efficiency of silicon solar cells", Optical Materials 145, 114501, 2023. https://doi.org/10.1016/j.optmat.2023.114501
[11] A. Flores-Pacheco, J. R. Montes-Bojórquez, M. E. Álvarez-Ramos and A. A. Ayón, "Down-shifting and antireflective effects of ZnO/PMMA thin films and their influence on silicon solar cells performance", Micro and Nano Engineering 15, 100128, 2022. https://doi.org/10.1016/j.mne.2022.100128
[12] C. K. Hong, H.-S. Ko, E.-M. Han, J.-J. Yun, et al., "Enhanced efficiency of dye-sensitized solar cells doped with green phosphors LaPO4: Ce, Tb or (Mg, Zn)Al11O19:Eu", Nanoscale Research Letters 8 (1), 219, 2013. https://doi.org/10.1186/1556-276X-8-219
[13] Q. Wu, X. Liu, B. Li, L. Tan, et al., "Eco-friendly and degradable red phosphorus nanoparticles for rapid microbial sterilization under visible light", Journal of Materials Science & Technology 67, 70-79, 2021. https://doi.org/10.1016/j.jmst.2020.04.084
[14] R. Kamal and H. Hafez, "Novel Down-converting single-phased white light Pr3+ doped BaWO4 Nanophosphors material for DSSC applications", Optical Materials 121, 111646, 2021. https://doi.org/10.1016/j.optmat.2021.111646
[15] X. Luo, J. Y. Ahn and S. H. Kim, "Aerosol synthesis and luminescent properties of CaAl2O4:Eu2+, Nd3+ down-conversion phosphor particles for enhanced light harvesting of dye-sensitized solar cells", Solar Energy 178, 173-180, 2019. https://doi.org/10.1016/j.solener.2018.12.029
[16] S. Khurshid, H. Latif, S. Rasheed, R. Sharif, et al., "Enhancement in absorption spectrum by ITO coated, down converting glass as a photoanode substrate for efficient PbS/CdS quantum dots sensitized ZnO nano-rods array solar cell", Optical Materials 124, 111991, 2022. https://doi.org/10.1016/j.optmat.2022.111991
[17] D. Zhou, D. Liu, G. Pan, X. Chen, et al., “Cerium and Ytterbium Codoped Halide Perovskite Quantum Dots: A Novel and Efficient Downconverter for Improving the Performance of Silicon Solar Cells”, Advanced Materials 29, 1704149, 2017. https://doi.org/10.1002/adma.201704149