Investigation of Co and Ni catalysts effect in carbon nanotubes synthesis and magnetic

Authors

Abstract

Carbon nanotubes (CNT) were synthesized by CVD method based on Ni(NO3)2.6H2O and Co(NO3)2.6H2O solution with two different ratios [Ni/Co = (1/ 0.5) , (1/ 0.0)]. We obtained the magnetic properties of the samples, such as coercivity field, saturate magnetization, retentivity magnetization and magnetic susceptibility by using of the magnetic hysteresis loops. It was found that carbon nano tubes were synthesized by using combination of Ni(NO3)2.6H2O and Co(NO3)2.6H2O catalysts, have much higher coercivity field, but less retentivity magnetization and saturation magnetization compared with the nanotubes were synthesized by using of the only Ni(NO3)2.6H2O catalyst

Keywords


[1]  S. Iijima, “Helical microtubules of graphitic carbon”, Nature 354 (1991) 56-58.
[2]    S.J. Tans, A.R.M. Verschueren, and C. Dekker, “Room temperature transistor based on a single carbon nanotube”, .Nature 393 (1998) 49-52.
[3]   P. Ajayan and O. Zhou, “Applications of Carbon Nanotubes, Carbon Nanotubes”. Top Appl. Phys. 80 (2001) 391-425.
[4]   E. Bakalis and F. Zerbetto, “Double-wall carbon nanotubes: The outer shell may pattern the structure of the inner one” Chem. Phys. Lett. 463 (2008) 139-140. 
[5]  T. Hemraj-Benny, T.J Bandosz, and S.S. Wong. “Effect of ozonolysis on the pore structure, surface chemistry, and bundling of single-walled carbon nanotubes”, J. Colloid Interface Sci. 317 (2008) 375-384.
[6]  J. Wu and L. Kong, “High microwave permittivity of multiwalled carbon nanotube composites”. Appl. Phys. Lett. 84 (2004) 4956-4958.
[7]  X.P. Gao, Y. Zhang, X. Chen, G.L.Pan, J. Yan, and F. Wu,. “Carbon nanotubes filled with metallic nanowires”. Carbon 42 (2004) 47-52.
[8]   Y.K. Kwon and D. Tomanek, “Electronic and structural properties of multiwall carbon nanotubes”, Physical Review B, 58 (1998) No. 24.
[9]     T. Ando, “Theory of Electronic States and Transport in Carbon Nanotubes”, Journal of the Physical Society of Japan 74, No. 3 (2005) 777– 817.
[10]  J.P. Lu, “Novel Magnetic Properties of Carbon Nanotubes”. Phys. Rev. Lett. 74, (1995) 1123-1126.
[12]   C.J. Lee, J. Park, and J.A. Yu, “Catalyst effect on carbon nanotubes synthesized by thermal chemical vapor deposition “, Chem. Phys. Lett. 360 (2002) 250–255.
[13]  T. Belin, and F. Epron, “Characterization methods of carbon nanotubes: a review “, Mat. Sci and Eng: B, 119 (2005) 105-118
[14]  P. Lambin, A. Loiseau, C. Culot, and L.P. Biro´, “Structure of carbon nanotubes probed by local and global”, Carbon 40 (2002) 1635–1648.
[15]   E. Pellicer, A.B. González-Guerrero, J. Nogués, L.M. Lechuga, and E. Mendoza., “Assessment of catalyst particle removal in multi-wall carbon nanotubes by highly sensitive magnetic measurements “, Carbon 47 (2009) 758 –763.
[16]  S. Singh, “Structural and Magnetic Study of an Electrodeposited Ni/Cu Thin Film by Neutron Reflectometry”, Electrochemical and Solid-State Letters 9, No. 3 (2006) J5-J8.
[17]     P. Dubey D. Muthukunaran, S. Dash, R. Mukhopadhyay, and S. Sarkar,” Synthesis and characterization of water-soluble carbon nanotubes from mustard soot”, Pramana , J. Phys. 65, No. 4 (2005) 681-697.
[18]   G. Singh, S. Priya, M.R. Hossu, S.R. Shah, S. Grover, A.R. Koymen, and R.L. Mahajan, “Synthesis, electrical and magnetic characterization of core-shell silicon carbo-nitride coated carbon nanotubes “, Materials Letters 63 (2009) 2435–2438.